First, we notice that the ladder forms the hypotenuse of a right triangle with the ground and the wall. Because we know an angle, the length of the hypotenuse, and we want the length opposite the angle, we want to use the sine function.
\begin{align*}
\sin(75^\circ) & = \frac{B}{16}\\
16\sin(75^\circ) & = B\\
15.45 & \approx B
\end{align*}
Thus the optimal distance to place the base of the ladder is 15.5 feet from the wall.